Krasnoyarsk, Krasnoyarsk, Russian Federation
employee
Russian Federation
UDK 630 Лесное хозяйство. Лесоводство
The ability of grinding equipment in the production of microcrystalline cellulose (MCC) to separate plant polymers into fibers, grind and develop certain properties in them can be used if it is impossible to minimize the concentration of acid. To obtain microcrystalline cellulose, samples (N = 6) of dry wood Picea abies (L.) H.KARST., Larix sibirica LEDEB., Populus tremula L. species were used. The samples were cooked in a laboratory autoclave, prehydrolysis grinding was carried out in a centrifugal grinding machine at a fibrous mass concentration of 6% and varying the degree of grinding from 15 to 85 degrees of Schopper Riegler (°SR). Chemical treatment of cellulose samples with different degrees of grinding was carried out with varying hydrolysis temperatures from 80 to 100 °C, hydrochloric acid concentrations from 54.75 to 91.25 g/l, and hydrolytic degradation time from 60 to 120 minutes. The dependences of the degree of polymerization (R2 = 0.93) and the degree of crystallinity (R2 = 0.99) on these factors are approximated by second-order regression equations and visualized as three-dimensional response surfaces. The optimal values of the hydrolysis variables are: hydrochloric acid concentration – 54.75 g/l, hydrolytic degradation time – 60 min, hydrolysis temperature – 80 °C, grinding degree – 85 °C. The degree of grinding of the fibrous mass has the greatest influence on the quantitative values of the degree of polymerization and the degree of crystallinity, the lowest is the temperature of hydrolysis. With an increase in the degree of grinding, a significant 2.7-fold decrease in the degree of polymerization occurs in MCC samples from P. abies and P. tremula wood. An increase in the degree of crystallinity (17%) and bulk density (20%) is observed to a greater extent in MCC samples from P. abies and L. sibirica wood. The use of prehydrolysis milling of cellulose in the process of obtaining MCC reduces the cost of chemical treatment by 1.7 times.
microcrystalline cellulose, Picea abies (L.) H.KARST., Larix sibirica LEDEB., Populus tremula L., prehydrolysis refining, degree of polymerization, degree of crystallinity
1. Biorazlagaemye materialy na osnove rastitel'nyh polisaharidov dlya upakovki pischevyh produktov. Chast' 1 / I. Yu. Potoroko, A. V. Malinin, A. V. Caturov, Udey Bagale // Vestnik Yuzhno-Ural'skogo gosudarstvennogo universiteta. Seriya: Pischevye i biotehnologii. 2020; № 2: S. 21-28. – DOI: http://doi.org/10.14529/food200203. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=42951866.
2. Vshivkov, S. A. Reologicheskie svoystva zhidkokristallicheskih rastvorov proizvodnyh cellyulozy / S. A. Vshivkov, E. V. Rusinova, A. S. A. Saleh // Vysokomolekulyarnye soedineniya. Seriya A. 2021; № 4: S. 243-248. – DOIhttps://doi.org/10.31857/S2308112021040088. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=45795102.
3. Tan W. Y., Gopinath S. C. B., Anbu P., Velusamy P., Gunny A. A. N., Chen Y., Subramaniam S. Generation of microcrystalline cellulose from cotton waste and its properties // BioResources. 2023; 8(3): 4884-4896. DOI: http://doi.org/10.15376/biores.18.3.4884-4896.
4. García Hernández M. A., Marure A. L., Neira Velázquez M. G., Mariano Torres J. A., Galvan A. A. Microcrystalline cellulose isolation – Proposed mechanism: Enhanced coupling // BioResources. 2023; 18(1): 1788-1802. DOI: http://doi.org/0.15376/biores.18.1.1788-1802.
5. Martakova, Yu. V. Gidrogeli na osnove rastitel'nyh cellyuloz i ih kompozity s nanochasticami serebra : dis. ... kand. him. nauk : 02.00.06 / Martakova Yuliya Vladimirovna. – In-t vysokomolekulyar. soedineniy. - Syktyvkar, 2018. - 153 s. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=54451226.
6. Momzyakova, K. S. Sovershenstvovanie tehnologii polucheniya cellyulozy iz travyanistyh rasteniy : dis. … kand. tehn. nauk: 05.17.06 / Momzyakova Kseniya Sergeevna. – Kazan', 2021. – 150 s. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=54419808.
7. Vliyanie nozhevogo sposoba razmola voloknistoy massy na process polucheniya poroshkovoy cellyulozy / Yu. D. Alashkevich, L. V. Yurtaeva, N. S. Reshetova, R. A. Marchenko // Himiya rastitel'nogo syr'ya. 2020; № 4: S. 493-499. – DOI: http://doi.org/10.14258/jcprm.2020048121. – Rezhim dostupa: https://www.elibrary.ru/vmyzac.
8. Pererabotka povrezhdennoy drevesiny kak faktor racional'nogo ispol'zovaniya prirodnyh resursov / E. R. Kolosova, V. A. Patrakov, E. V. Kaplev, D. S. Tarazeev // Molodye uchenye v reshenii aktual'nyh problem nauki : sbornik materialov Vserossiyskoy nauchno-prakticheskoy konferencii studentov, aspirantov i molodyh uchenyh (s Mezhdunarodnym uchastiem), Krasnoyarsk, 21–22 aprelya 2022 goda. – Krasnoyarsk: Federal'noe gosudarstvennoe byudzhetnoe obrazovatel'noe uchrezhdenie vysshego obrazovaniya "Sibirskiy gosudarstvennyy universitet nauki i tehnologiy imeni akademika M.F. Reshetneva", 2022; 194-196. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=49759509.
9. Malova, A. S. Ispol'zovanie poroshkovyh cellyuloznyh materialov v proizvodstve bumagi i kartona / A. S. Malova, V. N. Sunayt // Sovremennaya cellyulozno-bumazhnaya promyshlennost'. Aktual'nye zadachi i perspektivnye resheniya : Materialy II Mezhdunarodnoy nauchno-tehnicheskoy konferencii molodyh uchenyh i specialistov CBP, Sankt-Peterburg, 23 noyabrya 2020 goda. Tom I. – Sankt-Peterburg: Sankt-Peterburgskiy gosudarstvennyy universitet promyshlennyh tehnologiy i dizayna, 2020; 46-51. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=46185815.
10. Queiroz A. L. P., Kerins B. M., Yadav J. et al. Investigating microcrystalline cellulose crystallinity using Raman spectroscopy. Cellulose. 2021; № 28: 8971–8985. https://doi.org/10.1007/s10570-021-04093-1.
11. Hermawan, D., Lai, T. K., Jafarzadeh, S. J., Gopakumar, D. A., Hasan, M., Owolabi, F. A. T., Sri Aprilia, N. A., Rizal, S., and Abdul Khalil, H. P. S. Development of seaweed-based bamboo microcrystalline cellulose films intended for sustainable food packaging applications. BioRes. 2019; 14 (2): 3389-3410. DOI: http://doi.org/10.15376/biores.14.2.3389-3410.
12. Hou, W., Ling, C., Shi, S., and Yan, Z. Preparation and characterization of microcrystalline cellulose from waste cotton fabrics by using phosphotungstic acid // Int. J. Biol. Macromol. 2019; № 123: 363-368. DOI: http://doi.org/10.1016/j.ijbiomac.2018.11.112.
13. Kale, R. D., Bansal, P. S., and Gorade, V. G. Extraction of microcrystalline cellulose from cotton sliver and its comparison with commercial microcrystalline cellulose, J. Polym. Environ. 2018; № 26: 355-364. DOI: http://doi.org/10.1007/S10924-017-0936-2.
14. Boltovskiy, V. S. Sposoby polucheniya mikrokristallicheskoy cellyulozy / V. S. Boltovskiy // Trudy BGTU. Seriya 2: Himicheskie tehnologii, biotehnologiya, geoekologiya. 2021; № 1(241): S. 40-50. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=44888935.
15. Toptunov, E. A., Sevast'yanova, Yu. V. Poroshkovye cellyuloznye materialy: obzor, klassifikaciya, harakteristiki i oblasti primeneniya // Himiya rastitel'nogo syr'ya. 2021; № 4: S. 31-45. DOI: http://doi.org/10.14258/jcprm.2021049186. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=47446186.
16. Vanhatalo, K. A new manufacturing process for microcrystalline cellulose (MCC): A doctoral dissertation for the degree of Doctor of Science (Technology). Helsinki, 2019. 73 p. DOI: http://doi.org/10.1134/S1070427209030276.
17. Barud, H, Silva R, Barud H, Tercjak A, Guttierez J, Lustri W, et al. A multipurpose natural and renewable polymer in medical applications: Bacterial cellulose. Carbohydrate Polymers. 2018; № 153: 406-420. DOI: http://doi.org/10.1016/j.carbpol.2016.07.059.
18. Ilyas, R.A., Sapuan S.M., Ishak M.R., Zainudin E.S., Atikah M.S. Characterization of sugar palm nanocellulose and its potential for reinforcement with a starch-based composite. In: Sugar Palm Biofibers, Biopolymers, and Biocomposites. 1st ed. Boca Raton, FL: CRC Press/Taylor & Francis Group; 2018; №1: pp. 189-220. DOI: http://doi.org/10.1201/9780429443923-10.
19. Delignifikaciya rastitel'nogo syr'ya pod vozdeystviem mikrovolnovogo izlucheniya. Ik-spektry i indeksy uporyadochennosti cellyulozy / E. Yu. Kushnir, A. G. Shahova, N. G. Bazarnova [i dr.] // Himiya rastitel'nogo syr'ya. 2020; № 4: S. 101-107. – DOI: http://doi.org/10.14258/jcprm.2020048962. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=44529529.
20. Poluchenie mikrokristallicheskoy cellyulozy iz drevesiny osiny pod vozdeystviem mikrovolnovogo izlucheniya / T. S. Gen'sh, E. Yu. Kushnir, P. V. Kolosov, K. V. Gen'sh // Moy vybor - nauka! : sbornik materialov VI Regional'noy molodezhnoy konferencii, XLVI nauchnoy konferencii studentov, magistrantov, aspirantov i uchaschihsya liceynyh klassov, Barnaul, 17–27 aprelya 2019 goda. – Barnaul: Altayskiy gosudarstvennyy universitet. 2020; S. 1256-1261. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=43841476.
21. Poluchenie gidrolizovannoy cellyulozy iz drevesiny osiny i sosny pod vozdeystviem mikrovolnovogo izlucheniya / E. Yu. Kushnir, N. G. Bazarnova, T. S. Gen'sh, K. V. Gen'sh // Novye dostizheniya v himii i himicheskoy tehnologii rastitel'nogo syr'ya : Mater. VIII Vseros. konferencii s mezhdunarodnym uchastiem, Barnaul, 05–09 oktyabrya 2020 goda / pod red. N. G. Bazarnovoy, V. I. Markina. – Barnaul: Altayskiy gosudarstvennyy universitet. 2020; S. 43-45. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=44188333.
22. Sravnitel'nye issledovaniya fiziko-himicheskih svoystv i struktury hlopkovoy cellyulozy i ee modificirovannyh form / A. A. Atahanov, B. Mamadierov, M. Kuzieva [i dr.] // Himiya rastitel'nogo syr'ya. 2019; № 3: S. 5-13. – DOI: http://doi.org/10.14258/jcprm.2019034554. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=41311613.
23. Patent № 2804640 C2 Rossiyskaya Federaciya, MPK C08B 15/02. Sposob nepreryvnogo polucheniya mikrokristallicheskoy cellyulozy : № 2022106827 : zayavl. 15.03.2022 : opubl. 03.10.2023 / A. I. Sizov, A. A. Dobrovol'skiy, A. V. Muhamedshin, S. D. Pimenov ; zayavitel' Obschestvo s ogranichennoy otvetstvennost'yu "Kristacel". – 7 s. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=54674742.
24. Poluchenie poroshkovoy mikrokristallicheskoy cellyulozy iz drevesnoy cellyulozy i issledovanie ee svoystv / O. A. Noskova, F. H. Hakimova, R. R. Hakimov, E. A. Kataev // Nauka i tehnologii: modernizaciya, innovacii, progress : Sbornik nauchnyh trudov po materialam X Mezhdunarodnoy nauchno-prakticheskoy konferencii, Anapa, 27 dekabrya 2022 goda. – Anapa: Obschestvo s ogranichennoy otvetstvennost'yu «Nauchno-issledovatel'skiy centr ekonomicheskih i social'nyh processov» v Yuzhnom Federal'nom okruge. 2022; S. 62-67. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=50338313.
25. Kaplev, E. V. Sposoby polucheniya poroshkovyh cellyuloznyh materialov / E. V. Kaplev, L. V. Yurtaeva // Sostoyanie okruzhayuschey sredy, problemy ekologii i puti ih resheniya : Materialy Vserossiyskoy nauchno-prakticheskoy konferencii, Ust'-Ilimsk, 20–21 dekabrya 2021 goda. – Irkutsk: Baykal'skiy gosudarstvennyy universitet. 2022; s. 79-85. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=48215448.
26. Vliyanie nozhevogo i beznozhevogo sposobov razmola na voloknistyy material / A. V. Goncharov, O. N. Fedorova, R. A. Marchenko, Yu. D. Alashkevich // Lesnoy i himicheskiy kompleksy - problemy i resheniya : Sbornik mater. po itogam Vseros. nauch.-prakt. konferencii, Krasnoyarsk, 02–04 sentyabrya 2019 goda. – Krasnoyarsk, 2019. – S. 315-317. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=41219738.
27. Marchenko, R. A. Beznozhevaya obrabotka vtorichnogo voloknistogo syr'ya v CBP / R. A. Marchenko, V. I. Shurkina, A. A. Muravickaya // Reshetnevskie chteniya : Materialy XXIII Mezhdunarodnoy nauchno-prakticheskoy konferencii, posvyaschennoy pamyati general'nogo konstruktora raketno-kosmicheskih sistem akademika M.F. Reshetneva. V 2-h chastyah, Krasnoyarsk, 11–15 noyabrya 2019 goda / pod obsch. red. Yu. Yu. Loginova. Ch. 2. – Krasnoyarsk, 2019. – S. 98-99. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=41824511.
28. Poluchenie analiticheskoy zavisimosti prochnostnyh svoystv bumagi ot bumagoobrazuyuschih pokazateley voloknistoy massy / L. V. Yurtaeva, N. S. Reshetova, Yu. D. Alashkevich [i dr.] // Himiya rastitel'nogo syr'ya. 2020; № 4: s. 501-509. – DOI: http://doi.org/10.14258/jcprm.2020048583. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=44529573.
29. Kaplev, E. V. Vliyanie rezhima razmola na fiziko-mehanicheskie svoystva sul'fatnoy belenoy cellyulozy / E. V. Kaplev, L. V. Yurtaeva, Yu. D. Alashkevich // Problemy mehaniki cellyulozno-bumazhnyh materialov : Mater. V Mezhdunar. nauch.-tehn. konferencii, posvyaschennoy pamyati professora V.I. Komarova, Arhangel'sk, 11–14 sentyabrya 2019 goda. – Arhangel'sk: Severnyy (Arkticheskiy) federal'nyy universitet imeni M.V. Lomonosova. 2019; s. 87-92. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=42408660.
30. Razmol listvennoy cellyulozy s ispol'zovaniem garnitury s krivolineynoy formoy nozhey / E. M. Batrakevich, V. I. Shurkina, R. A. Marchenko, N. E. Shumarina // Reshetnevskie chteniya : Materialy XXV Mezhdunarodnoy nauchno-prakticheskoy konferencii, posvyaschennoy pamyati general'nogo konstruktora raketno-kosmicheskih sistem akademika M.F. Reshetneva. V 2-h chastyah, Krasnoyarsk, 10–12 noyabrya 2021 goda / Pod obschey redakciey Yu.Yu. Loginova. Ch. 2. – Krasnoyarsk, 2021. – S. 88-89. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=47712294.
31. Voronin, I. A. Mehanizm razmola na nozhevom centrobezhno-razmalyvayuschem apparate / I. A. Voronin, Yu. D. Alashkevich, V. A. Kozhuhov // Himiya rastitel'nogo syr'ya. 2020; № 4: S. 485-492. – DOI: http://doi.org/10.14258/jcprm.2020048164. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=44529571.
32. Vliyanie razmola odnoletnih rastitel'nyh polimerov na process polucheniya melkodispersnoy cellyulozy / L. V. Yurtaeva, Yu. D. Alashkevich, E. V. Kaplev, E. A. Slizikova // Hvoynye boreal'noy zony. 2023; № 4: 361-368. – DOI: http://doi.org/10.53374/1993-0135-2023-4-361-368. – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=54398267.
33. Patent № 2803626 C1 Rossiyskaya Federaciya, MPK D21C 1/04. Sposob polucheniya mikrokristallicheskoy cellyulozy : № 2023103933 : zayavl. 20.02.2023 : opubl. 18.09.2023 / Yu. D. Alashkevich, V. I. Kovalev, L. V. Yurtaeva, E. V. Kaplev, E. A. Slizikova; zayavitel' Federal'noe gosudarstvennoe byudzhetnoe obrazovatel'noe uchrezhdenie vysshego obrazovaniya "Sibirskiy gosudarstvennyy universitet nauki i tehnologiy imeni akademika M.F. Reshetneva". – Rezhim dostupa: https://www.elibrary.ru/item.asp?id=54659924.
